|
Material constants and kinetic parameters used in the simulation [15]
|
Parameter
|
|
Value
|
|
k0
|
Standard rate constant
|
1.5 × 10-3 (m/s)
|
εB
|
Association factor
|
2.6
|
α
|
Charge transfer coefficient
|
0.5
|
T
|
Absolute temperature
|
298 (K)
|
μ
|
Viscosity
|
1.1 (cP)
|
VA
|
Molar volume
|
0.1176 (m3/mol)
|
rp
|
Pore radius
|
200 × 10-9 (m)
|
L
|
Pore length
|
5 × 10-6 (m)
|
k
|
Surface reaction rate constant
|
5 × 10-4, 5 × 10-5, 5 × 10-7 (m/s)
|
MB
|
Molecular weight of water
|
18
|
R
|
Gas constant
|
8.31 (J/K. mol)
|
F
|
Faraday constant
|
9.648 × 104 (C/mol)
|
DF
|
Diffusivity of ferro- and ferri-cyanide
|
8 ×10-10m2/s
|
|
Anandan et al. Journal of Biological Engineering 2007 1:5 doi:10.1186/1754-1611-1-5
|